There is no problem with 3.Nc3 for white in the Slav Defense. It may lead to sharper play than usual if black accepts the (temporary) pawn sacrifice (3...dxc4). Super GMs play that move (3.Nc3) fairly regularly, too -- it's not just Aronian and not just yesterday. Often, the line just transposes to the more typical lines after 3.Nf3.
What is the big deal with 3...e5, according to your local master? That black is allowed to play it, compared to the lines after 3.Nf3 -- okay. But what is black's gain, according to this person?
A sometimes-expert at the local chess club consistently plays the Slav Defense. The lone master at the club has shown us why one does not play 1 d4 d5 2 c4 c6 3 Nc3: 3...e5. But Aronian just played 3 Nc3 against Vallejo Pons, so I assume there's a refutation of 3...e5. Does anyone know it?