White has to survive two "50/50" guesses to win. If black wins either, then black wins the game.
Therefore, black plays the first "50/50" (69.... Kxf6) 1/3 of the time, and the safer option (69... g5) 2/3 of the time.
If black goes for 69.... Kxf6 and white doesn't counter 69. Kxf6 with 68...Kg6, then black wins, otherwise white wins.
If black goes for 69...g5 and white doesn't counter 69... g5 (with 68... Kh6 or another king move that allows 70. Kxg5), then black wins. If white does counter it, then black wins 50% of the time, with the next 50/50 that happens over the fight for white trying to win the e5 pawn.
UPDATE AFTER 10 COMMENTS: Black can actually win 75% of the time.
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66... Black to play: Does Black win 66.66% of the time with best play from both sides? https://www.chess.com/variants/fog-of-war/game/71542170/131/1
Or does the possibility of black going for Kxd3 change things? (I don't think it does, since I don't think black wins >66% of the time in Kxd3 endgames.)