You go to your settings (accout > online chess), and scroll down until you find the little box that says "Challenge New Members". Unclick the box (if you want to quit the program), or click the box (if you want to start it). That is how to do that in a nutshell.
challenging new members
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chess.com provides a setting where you can automatically challenge every new member, i know because i did it once before, does anyone know how to access it? thanks, too many possibilities and stuff on this site.