Queen v Rook Position

Any move is bad in the sense that Black is going to lose, so it's only a question of how quickly.
Any moves but Kd7 or Kc8 lose the rook PDQ, but there's not a lot between those two moves.
Easiest thing is to follow the lines suggested by Syzygy here. The DTZ lines may be more of interest than the DTM because Black will resign once you reach KQK.

IMO one of the most pointless endgames you can study. You have a huge material advantage and very likely it was possible to keep one or two pawns and finish this game with R+2P vs R or something like this.
The other point is nobody in the world is able to find the best defensive moves.