I guess my general rule is: If there is no tactic that will allow the queen to win any additional material, then I prefer the 2 rooks. For example, and in an endgame with 2 rooks + 2 pawns vs queen + 2 pawns, if neither side has any way to force material exchange for the time being, I'd definitely prefer the rooks. The queen is just an added target most of the time...
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Would you trade your queen for 2 rooks?