Hmm, no position given.
I'm guessing you're asking about the Sicilian.
A Scheveningen type set up (e6) vs a sveshnikov type set up (e5).
Each has its pros and cons. Maybe the most notable is when you play e5 the d5 square becomes a "hole" (none of your pawns can defend it) and so d5 is a good outpost square for white. Also your d6 pawn may come under pressure when it's very difficult to advance it because white will own d5.
When you play e6 the pawns are abreast and work together to control many squares. It's a smaller center, but a very solid structure and play usually develops on the wings. Black also reserves the possibility to break in the center with d5 later (the e6 pawn helps control d5). He can also play e5 later.
Why is pawn to e6 a better move than pawn to e5 in this instance?
Doesnt e5 give centre control and attack d4 knight?