There are two parts to this; it isn’t just the second law of thermodynamics. We can have entropy, but to have that coupled with the need to harness energy and make it useful simultaneously, we must direct material into a meaningful layout activity to channel energy! You think the material world would come together in such a way without falling apart isn't also in play too. In addition, the channeling must be done in such a way that it will direct highly complex work to be done with precision, equipped with error checking, ensuring that it is done correctly. Do you think that is the byproduct of an unquided process without goals or outside interference?
Seriously?!?!
The natural thing in this universe is decay; the unnatural thing is low entropy and high energy coming together to form functionally complex systems without an external intervention.
That was my hang-up the last two years that I identified as a creationist. It took half a bottle of beer poured into the sink by a biologist as we were cleaning his apartment to put my misunderstanding to rest. Of course, he explained the Second Law of Thermodynamics with some clarity while dumping the beer.