1.Qh6 is a threat. More specifically, it is a mate in one threat.
I suspect that if you even looked at 1.Qh6 you simply said, "I can't play that, he'll take my queen!"
That's exactly what went through my mind regarding Qh6, it was even subconscious. First step in blunder check is about avoiding moving a piece towards a square where it will be captured on the next move. How often do you calculate moves that involves placing a queen right in front of enemy pawns? Or developing a piece where it will be lost on the next move? I naturally don't even consider those moves, it would make me exhausted to consider them during a full game.
But in this case, Qh6 is a threat in deed. I guess i need to sharpen my alarm bell for when it's time to look for this kinds of tactics/threats. Having several active pieces & being in a sharp position is one of those alarm bells i suppose.
Sure, ideally you do it in real games too.