This is a common chess-equivalent to an "Old Wive's Tale". Amateurs are misguided into believing that the Caro-Kann and Slav are similar, along with the French and QGD, King's Indian and Pirc, etc.
Well, quite frankly, none of those pairs are similar. For example, if you are a French player, I would recommend the King's Indian Defense. Why, you say? Because they both lead to frequent instances of what is known as a "Blocked Center". Both openings deal with pawn chains, attacking on the wing, attacking the base of the pawn chain, etc. Those that play the closed Ruy Lopez ought to play the Orthodox QGD. Both deal with pawn levers and strongpoints. Both are also very positional in nature. If I had to compare the Pirc to a Queen Pawn Opening, it wouldn't be the King's Indian. Think about the nature of the Pirc. Semi-Open, highly tactical. Yet, at the same time, not erratic like say, the Lativan. What QP opening fits this description? Probably the Grunfeld would be the closest (King's Indian leads to a blocked center, Leningrad Dutch is a tad too eratic.
So this ought to explain why the Slav and Caro-Kann are, in reality, not similar. They both feature a pawn on c6 and another on d5. Beyond that, they are two completely different openings.
GM Malakhov says he decided on a6 Slav. I wondered why no mention of Caro Kann, since it seems similar. Is Caro Kann a lot different, or are the similarities only superficial?
http://www.chessintranslation.com/2010/09/vladimir-malakhov-chess-player-nuclear-physicist/