Funny, the exact thing happened to me when I had just started chess, perhaps over 1.5 years ago now. The school champion placed a piece en-prise, and heaved a sigh. (A face-palm moment, if you will.) Of course, I immediately captured the piece. Two or three seconds later, I had a 0 next to my name and I was out of the School Knockout tournament. (The following year, my crafty opponent had left the school, I was much stronger, and went on to win both that and the School Championship as well.)
But on other areas of psychology... I find the best way to win is to flash 'Hang Queen' multiple times in the blink of an eye, and just allow my opponents AWP to take over.
Depends, online or otb? If someone spoke to me otb I would have shushed them and possibly called the arbitrator if he kept at it, online I can't say I really care.