Giuoco Piano Game: Giuoco Pianissimo, Italian Four Knights, Canal Variation
Longest opening name?
it's (probably) Giuoco Piano Game: Giuoco Pianissimo, Italian Four Knights, Canal Variation standing at 63
(edit: it's 66, i can't count)
(edit: still not sure. i'm too lazy to count)

“Queen's Indian Defense: Fianchetto, Nimzowitsch Variation, Quiet, Check Variation, Intermezzo Line” (98)
longest name i can think of is something from either the ruy lopez or queens gambit but i dont rly remember