Trade when you think your opponent's piece is better than yours.
Don't trade your good or active pieces for your opponent's bad ones.
The numerical values of pieces is a guide,not written in stone. Sometimes a lowly pawn can have more value than a Queen.
*stands in front of crowd* My name is Ladya79, and I can't exchange pieces well!
*crowd* Hi, Ladya79...
Here's my sad tale of woe: I know the values of the pieces, and so I know, all other things being equal, what pieces to trade for what (knight for bishop, rook for bishop and 2 pawns, a queen for nothing else but my opponent's queen). My trouble comes in when I'm trying to trade, say, a knight for a bishop and all of a sudden I lose one of my OTHER pieces that I'm really not counting on losing! :P Sometimes I'm only down a pawn, but I'm still down. It's hard to come back from.
So, when would you guys exchange pieces? When would you not? I need an intervention! I've taken the first step already:
1. I am powerless before the temptation to trade and end up -1, -3, -5, -8...!