First you should go to http://www.chess.com/livechess and click on the green "Play Live Chess" button and then once you are logged into the Live Chess you will see a "Start New Game" button which you can click to get a game in the Live Chess.
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Hi all..i jst added in today n cant fig how to challenge a player for live chess...everytime i press challenge which is on d left..it cmes down to online game with 3 day a move...can someone help me and show how to select a player and throw him a challenge for a live game that instant...thanks