Yes, you can challenge one another in live chess too. You both go to live chess, then you (or he) click on his name and choose "challenge to a game" from the menu that appears, then set up the game details and click "create new game".
Chess with friends
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Thanks for your help!.
I have a friend recently signed up, but not a paid member. Is there a way we can play each other in a quick game, not the day per move option?.