I'd advise against taking up a mindset that any move that doesn't look to be a book move can be "punished." It is easy to develop tunnel vision and underestimate the point of the move and your opponent in the process.
The rationale of 2.e5 is most likely that it gets a French Defense player who relies on memorization out of book and into unfamiliar territory. I don't play the French but if I were black, the two moves I would consider are 2...d5 and 2...c5. If I play 2...c5, I'm looking at preventing the d4-e5 pawn chain and will prepare to attack the e5 pawn with moves like Nc6, Qc7 and maybe Nge7-g6.
What is the best way to punish e5 after e4, e6 in the french defense. What is the rationale behind the move e5 in this context anyway?