What makes a move suboptimal ?
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Definition 1. The optimality factor (op) of an opening / position is just the number of optimal moves.
The optimality factor of a k-acute opening
https://www.chess.com/forum/view/chess-openings/acuteness-of-openings
is equal to k. A move will be considered optimal if it within 0.1-0.2 of the best evaluation. Well, it's somewhat ambiguous depending on engines, depth etc. I'll use Stockfish 8 here (d=20, 9 lines) and elsewhere (d=20/20, 5 lines).
The optimality factor of the initial position is equal to 3+ (optimal moves are, at least, 1. d4, 1. e4 and 1. Nf3). Here are optimality factors of most popular openings in 2 plies:
(to be continued)
All these op-values are debatable.