(I play the Polerio Defense for Black a lot with 6...c6)
Objectively, I think 6...Bd7 could be okay for Black; especially as a surprise weapon to avoid theory. However, positionally speaking: I don't think it really "solves" anything that 6...c6 doesn't.
The problem is that Black has sacrificed a pawn already (and in some mainlines even a second pawn later) and relies on the initiative and piece development to get compensation. If you play 6...Bd7 as a repertoire choice, then you will probably find out that Black struggles to get something long lasting from this opening because you are trading Bishops. With this "simple exchange" you are taking pieces off of the chess board, but this arguably helps White more here! The reason is because Black has sacrificed material already. You have less attacking potential with less pieces on the board and you also usually do not want to be trading down into an endgame when you are already down in material.
You can experiment with this opening idea (6...Bd7), but I don't think it is in the spirit of this opening. You can perhaps switch opening choices or decide to go full force into the sharp lines after 6...c6, but this latter option is not for the faint of heart and you may end up sacrificing even more material a few moves later.
Arguably, 6...c6 is better; however, I often struggle to convert the positional advantage into anything concrete. Is it safer to just play 6...Bd7 so as to avoid losing material? Will I still lose material somehow, or will the game still be okay?
Thanks in advance! =)