I'd be surprised if the majority of GM titles were earned before the age of 20.
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Yesterday I have read a couple of comments in a website about a player who after only recently finally released from the shackles of study and work (his employers blessed his ambitions) decides to go get the GM status. He's in his 20s and in the 2006 Olympiad in Turin even beat Korchnoi. A couple of people hiding behind near anonymous names started dissing him before he had a chance to prove anything. But one commentor pointed that there were many people who got their GM status later in life.
http://blog.gilachess.com/mas-is-458-in-dubai/#comment-1774
Is it still possible to get it in his 20s?