I find this a lot too, I think it's because in a lot of cases the top correspondence (turn-based) players rely extremely heavily on databases, opening books, and the ability to analyze the board (move the pieces around). Once you take these tools away from them they are like fish out of water. Either these tools have become a crutch of sorts and they can't play well without them or they simply do not wish to improve their OTB chess skills. I noticed this a lot at Gameknot as well when I used to play there.
I agree though the discrepancy is odd because with all the skill and deep understanding of chess some of these high rated players display in their turn-based games, you'd think they'd be able to carry at least a good portion of it over to Live chess.
Saw quite a few 2000+ at online chess yet with horrible ratings/play at live chess.
What might be the reason?